Multifunctional GFRC composites: PEDOT: PSS-driven dielectric enhancement for energy storage and sensing applications

Basit Öğe Kaydı
dc.contributor.authorDemir, Ahmet
dc.contributor.authorMusatat, Ahmad Badreddin
dc.contributor.authorSubaşı, Azime
dc.contributor.authorRamazanoğlu, Doğu
dc.contributor.authorDehgan, Haydar
dc.contributor.authorMaraşlı, Muhammed
dc.contributor.authorGencel, Osman
dc.contributor.authorSubaşı, Serkan
dc.date.accessioned2025-09-11T09:41:29Z
dc.date.available2025-09-11T09:41:29Z
dc.date.issued2026
dc.departmentFakülteler, Mühendislik Fakültesi, Malzeme Bilimi ve Nanoteknoloji Mühendisliği Bölümü
dc.description.abstractThis study presents a comprehensive investigation into the development and characterization of multifunctional Glass Fiber Reinforced Cement (GFRC) composites enhanced with Poly(3,4-ethylenedioxythiophene):polystyrene sulfonate (PEDOT: PSS) to impart advanced electrical properties. We systematically analyzed the influence of PEDOT: PSS concentration (0–15 wt %) and curing age on the dielectric behavior of these novel composites, evaluating their capacitance, dielectric constant, loss factor, and electrical modulus across a broad frequency range (10 Hz-10 MHz). The integration of PEDOT: PSS significantly modified the material's electrical characteristics, demonstrating concentration-dependent variations and complex relaxation mechanisms dominated by Maxwell-Wagner interfacial polarization. The optimized P2 formulation (10 wt % PEDOT: PSS) exhibited superior electrochemical performance, maintaining the highest capacitance values and achieving a peak dissipation factor (tan δ) of 0.43 ± 0.02 at day 15, representing a 185 % enhancement over unmodified GFRC. EDX analysis confirmed successful polymer incorporation, with P2 exhibiting the highest carbon content (5.8 wt %) and sulfur content (1.8 wt %), indicating optimal dispersion. Equivalent circuit models were established and validated (R2 > 0.98), providing insights into complex charge transport mechanisms within this hybrid material. Microstructural analyses via scanning electron microscopy revealed significant morphological modifications, including the formation of crystalline and plate-like structures, while complementary FT-IR and TGA analyses confirmed polymer-cement interaction stability and thermal stability up to 450 °C. These findings establish fundamental design principles for creating electrically conductive cementitious materials with tunable dielectric properties, enabling strategic deployment in innovative infrastructure systems, energy storage devices, and electromagnetic shielding technologies.
dc.identifier.doi10.1016/j.matchemphys.2025.131512
dc.identifier.issn0254-0584
dc.identifier.scopus2-s2.0-105014763875
dc.identifier.scopusqualityQ1
dc.identifier.urihttps://doi.org/10.1016/j.matchemphys.2025.131512
dc.identifier.urihttps://hdl.handle.net/11501/2376
dc.identifier.volume347
dc.identifier.wosWOS:001568842800001
dc.identifier.wosqualityQ2
dc.indekslendigikaynakScopus
dc.indekslendigikaynakWeb of Science
dc.institutionauthorRamazanoğlu, Doğu
dc.institutionauthorid0000-0002-6356-5792
dc.language.isoen
dc.publisherElsevier Ltd
dc.relation.ispartofMaterials Chemistry and Physics
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.subjectDielectric Properties
dc.subjectGlass Fiber Reinforced Concrete
dc.subjectPoly(3,4-Ethylenedioxythiophene)
dc.subjectSmart Infrastructure
dc.titleMultifunctional GFRC composites: PEDOT: PSS-driven dielectric enhancement for energy storage and sensing applications
dc.typeArticle

Dosyalar

Orijinal paket
Listeleniyor 1 - 1 / 1
Kapalı Erişim
İsim:
Tam Metin / Full Text.pdf
Boyut:
24.62 MB
Biçim:
Adobe Portable Document Format
İndir
Lisans paketi
Listeleniyor 1 - 1 / 1
Kapalı Erişim
İsim:
license.txt
Boyut:
1.17 KB
Biçim:
Item-specific license agreed to upon submission
Açıklama:
İndir

Koleksiyon

Mühendislik Fakültesi Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu
WoS İndeksli Yayınlar Koleksiyonu