Chemical and vibrational criteria for identifying early sèvres factory porcelain productions

dc.contributor.authorColomban, Philippe
dc.contributor.authorŞimşek Franci, Gülsu
dc.contributor.authorGerken, Mareike
dc.contributor.authorGironda, Michele
dc.contributor.authorMesqui, Viviane
dc.date.accessioned2025-01-09T05:58:05Z
dc.date.available2025-01-09T05:58:05Z
dc.date.issued2024
dc.departmentFakülteler, Mühendislik Fakültesi, Metalurji ve Malzeme Mühendisliği Bölümü
dc.description.abstractThirteen porcelains assigned to Sèvres factory productions and a few references to the other contemporary factories (Chantilly, Limoges, and Venice) have been studied on-site with a portable X-ray fluorescence (pXRF) spectrometer in order to control the provenance attribution. Characteristic XRF signals of major elements (Si, Ca, K, Pb) and minor/trace (Au, Bi, As, Ti, Co, Cu, Zn, Ni, Y, Zr, Rb, and Sr) elements are compared for the paste, blue mark, various glazed (colored) areas, and gilding. The comparison of peak intensities clearly distinguishes different types of hard- and soft-paste porcelain, made from either similar or distinct raw materials. The analysis of transition elements associated with cobalt identifies three types of cobalt blue and reveals that du Barry-style decoration on certain artifacts was typical of 19th-century production. On-site comprehensive studies of the two famous Etruscan-style breast bowls from Rambouillet Castle dairy, using pXRF and Raman spectroscopy, confirm the use of soft-paste porcelain for the cup and hard-paste for its support, providing detailed information on the use of gold nanoparticles in the burgundy-colored decoration.
dc.description.sponsorshipAgence Nationale de la Recherche (ANR) ; Agence nationale pour le developpement de la recherche en sante (ANDRS)
dc.identifier.doi10.3390/ceramics7040120
dc.identifier.endpage1927
dc.identifier.issn2571-6131
dc.identifier.issue4
dc.identifier.scopus2-s2.0-85213477897
dc.identifier.scopusqualityQ2
dc.identifier.startpage1905
dc.identifier.urihttps://doi.org/10.3390/ceramics7040120
dc.identifier.urihttps://hdl.handle.net/11501/1588
dc.identifier.volume7
dc.identifier.wosWOS:001383773300001
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.institutionauthorŞimşek Franci, Gülsu
dc.institutionauthorid0000-0001-9050-5819
dc.language.isoen
dc.publisherMultidisciplinary Digital Publishing Institute (MDPI)
dc.relation.ispartofCeramics
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/openAccess
dc.subjectPorcelain
dc.subjectpXRF
dc.subjectRaman
dc.subjectPaste
dc.subjectGlaze
dc.subjectCobalt
dc.subjectGold
dc.subjectPink
dc.titleChemical and vibrational criteria for identifying early sèvres factory porcelain productions
dc.typeArticle

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