Production of B4C-TiB2 composite powder by self-propagating high-temperature synthesis

Basit Öğe Kaydı
dc.authoridBugdayci, Mehmet/0000-0001-6276-9251
dc.authoridCOBAN, OZAN/0000-0002-1506-4619
dc.authorwosidBugdayci, Mehmet/AFE-3282-2022
dc.authorwosidÇoban, Ozan/JED-3718-2023
dc.contributor.authorCoban, Ozan
dc.contributor.authorBugdayci, Mehmet
dc.contributor.authorAcma, M. Ercan
dc.date.accessioned2024-06-13T20:17:53Z
dc.date.available2024-06-13T20:17:53Z
dc.date.issued2022
dc.departmentİstanbul Gedik Üniversitesien_US
dc.description.abstractAdvanced ceramics find significant application areas due to their superior mechanical, electrical, magnetic chemical and thermal properties. By combining these materials, significant properties can be obtained as a result of production of the composites of hard metal compounds in nanoscale dimensions. Self-propagated high-temperature synthesis (SHS) is one of the prominent methods for the production of such nanoparticles. SHS is a combustion synthesis method. In this study, nanocomposite powders of B4C-TiB2 were synthesized by SHS method. FactSage software was used for thermochemical simulation and computational stoichiometric optimization. In the experimental step, 2 different SHS sets were prepared. In the first stage, B4C and TiB2 powders were synthesized. The B4C-TiB2 composite was produced in the final set of experiments. Then, production parameters of B4C-TiB2 composite powders, from B2O3, TiO2, and carbon black, were investigated. Magnesium powder was used as reductant agent. Afterwards, HCl leaching process was performed, and acid concentration was optimized. The effect of carbonic acid and H2O2 addition on dissolution of undesired phases was also been investigated as a new method. Products were characterized by XRD, SEM and BET analysis. B4C-TiB2 composite powder with quite high surface area, fine particle size and high porosity could be synthesized with reasonable purity. According to the results, the optimum molar ratios were determined as TiO2:B2O3:Mg:C = 1:3:12:1.6. Optimum acid concentration was found to be 10.5 M for leaching process, and carbonic acid addition on leaching step found to be effective on TiO2 removal. The highest purity could be obtained with 50%-50% stoichiometry. It has also been determined that the synthesis of B4C-TiB2 composite powder has a positive effect on both the chemical content and the morphology that will increase the sintering ability.en_US
dc.identifier.doi10.1007/s41779-022-00714-5
dc.identifier.endpage791en_US
dc.identifier.issn2510-1560
dc.identifier.issn2510-1579
dc.identifier.issue3en_US
dc.identifier.scopus2-s2.0-85127112663en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage777en_US
dc.identifier.urihttps://doi.org/10.1007/s41779-022-00714-5
dc.identifier.urihttps://hdl.handle.net/11501/1134
dc.identifier.volume58en_US
dc.identifier.wosWOS:000780290500001en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherSpringeren_US
dc.relation.ispartofJournal of the Australian Ceramic Societyen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectCombustion Synthesisen_US
dc.subjectSelf-Propagating High-Temperature Synthesisen_US
dc.subjectShsen_US
dc.subjectBoron Carbideen_US
dc.subjectTitanium Diborideen_US
dc.subjectNanoparticle Synthesisen_US
dc.subjectTitanium Diboride Powdersen_US
dc.subjectBoron-Carbideen_US
dc.subjectTib2 Powderen_US
dc.subjectCombustionen_US
dc.subjectShsen_US
dc.subjectConsolidationen_US
dc.subjectPhaseen_US
dc.subjectB4cen_US
dc.titleProduction of B4C-TiB2 composite powder by self-propagating high-temperature synthesisen_US
dc.typeArticleen_US

Dosyalar

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu