Synthesis, Preparation, and Characterization of Liquid Crystal/Organo-Montmorillonite Nanocomposites

Küçük Resim Yok

Tarih

2015

Dergi Başlığı

Dergi ISSN

Cilt Başlığı

Yayıncı

Taylor & Francis Ltd

Erişim Hakkı

info:eu-repo/semantics/closedAccess

Özet

A new chiral calamitic liquid crystal 4 '-((S)-3,7-dimethyloctyloxy)phenyl 4-(10-undecen-1-yloxy)benzoate (DOPUB) has been synthesized and characterized by spectroscopic methods (H-1-NMR and C-13-NMR). The focus is on the preparation of the nanocomposites of new chiral calamitic liquid crystal DOPUB/Organo-montmorillonite clay (OMMT) by solution intercalation method addition with OMMT contents 2.5, 5, and 7.5 wt% and determination of the morphology, thermal behavior, and crystalline properties of liquid crystal DOPUB/OMMT. Montmorillonite (MMT) modified by cationic surfactant cetyltrimethylammonium bromide (CTAB) for increasing the interaction of clay with DOPUB liquid crystal. The characterization of clay minerals and nanocomposites was investigated by X-ray diffraction. The mesomorphic behavior of liquid crystal (DOPUB) and the nanocomposites was investigated by differential scanning calorimetry (DSC) and optical polarizing microscopy (PM).

Açıklama

Anahtar Kelimeler

Montmorillonite, Nanocomposites, Liquid Crystal, Bent-Core Molecules, Crystalline Phases, Chirality

Kaynak

Molecular Crystals and Liquid Crystals

WoS Q Değeri

Q4

Scopus Q Değeri

Q4

Cilt

607

Sayı

1

Künye